Вивчення характеристик Ni(OH)2, отриманного в щілинному діафрагмовому електролізері при різних концентраціях сульфату натрію

В. Л. КОВАЛЕНКО, В. А. КОТОК

Анотація


Вивчені структурнітаелектрохімічні характеристики зразків гидроксиду нікелю, синтезованих в щілинному діафрагмовому електролізері в присутності в католіті сульфату натрію різної концентрації. Показана можливість синтезу высоко електрохімічно активного гідроксиду нікелюз оптимальною кристалічною структурою та кристалічністю при різному  вмісті сульфату натрія. Негативного впливу сульфату натрія не виявлено. Отримані дані дозволятьстворити високоефективну промислову технологію безперервногоелектрохімического отримання гідроксиду нікелю

Ключові слова


гідроксид нікелю; щілинний діафрагмовий електролізер; лужні акумулятори; кристалічність; циклічна вольтамперограма

Повний текст:

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Посилання


Posada, J. O. G., Rennie, A. J. R., Villar, S. P., Martins, V. L., Marinaccio, J., Barnes, A., … Hall, P. J. (2017). Aqueous batteries as grid scale energy storage solutions. Renewable and Sustainable Energy Reviews, 68, 1174–1182. doi: 10.1016/j.rser.2016.02.024

Hall, D. S., Lockwood, D. J., Poirier, S., Bock, C., MacDougall, B. R. (2012). Raman and Infrared Spectroscopy of α and β Phases of Thin Nickel Hydroxide Films Electrochemically Formed on Nickel. The Journal of Physical Chemistry A, 116 (25), 6771–6784. doi: 10.1021/jp303546r

Hu, M., Yang, Z., Lei, L., Sun, Y. (2011). Structural transformation and its effects on the electrochemical performances of a layered double hydroxide. Journal of Power Sources, 196 (3), 1569–1577. doi: 10.1016/j.jpowsour.2010.08.041

Vidotti, M., Torresi, R., De Torresi, SIC. (2010). Nickel hydroxide modified electrodes: a review study concerning its structural and electrochemical properties aiming the application in electrocatalysis, electrochromism and secondary batteries. Quim Nova, 33, 2176–2186.

Kovalenko, V. L., Kotok, V. A., Sykchin, A. A., Mudryi, I. A., Ananchenko, B. A., Burkov, A. A., … Henn, F. (2016). Nickel hydroxide obtained by high-temperature two-step synthesis as an effective material for supercapacitor applications. Journal of Solid State Electrochemistry, 21 (3), 683–691. doi: 10.1007/s10008-016-3405-2

Кovalenko, V., Kotok, V., Bolotin, O. (2016). Definition of factors influencing on Ni(OH)2 electrochemical characteristics for supercapacitors. Eastern-European Journal of Enterprise Technologies, 5 (6 (83)), 17–22. doi: 10.15587/1729-4061.2016.79406

Solovov, V. A., Nikolenko, N. V., Kovalenko, V. L., Kotok, V.A., Girenko, D.V. (2017) Formation mechanism of nickel hydroxide in system Ni(NO3)2–NaOH. Bulletin of NTU "KhPI". Series: New solutions in modern technologies., 7 (1229), 199–204.

Ramesh, T. N., Kamath, P. V. (2006). Synthesis of nickel hydroxide: Effect of precipitation conditions on phase selectivity and structural disorder. Journal of Power Sources, 156 (2), 655–661. doi: 10.1016/j.jpowsour.2005.05.050

Hu, B., Chen, S.-F., Liu, S.-J., Wu, Q.-S., Yao, W.-T., Yu, S.-H. (2008). Controllable Synthesis of Zinc-Substituted α- and β-Nickel Hydroxide Nanostructures and Their Collective Intrinsic Properties. Chemistry - A European Journal, 14 (29), 8928–8938. doi: 10.1002/chem.200800458

Gong, L., Liu, X., Su, L. (2011). Facile Solvothermal Synthesis Ni(OH)2 Nanostructure for Electrochemical Capacitors. Journal of Inorganic and Organometallic Polymers and Materials, 21 (4), 866–870. doi: 10.1007/s10904-011-9519-1

Yang, L.-X., Zhu, Y.-J., Tong, H., Liang, Z.-H., Li, L., Zhang, L. (2007). Hydrothermal synthesis of nickel hydroxide nanostructures in mixed solvents of water and alcohol. Journal of Solid State Chemistry, 180 (7), 2095–2101. doi: 10.1016/j.jssc.2007.05.009

Xu, L., Ding, Y.-S., Chen, C.-H., Zhao, L., Rimkus, C., Joesten, R., Suib, S. L. (2008). 3D Flowerlike α-Nickel Hydroxide with Enhanced Electrochemical Activity Synthesized by Microwave-Assisted Hydrothermal Method. Chemistry of Materials, 20 (1), 308–316. doi: 10.1021/cm702207w

Fomanyuk, S. S., Krasnov, Y. S., Kolbasov, G. Y. (2013). Kinetics of electrochromic process in thin films of cathodically deposited nickel hydroxide. Journal of Solid State Electrochemistry, 17 (10), 2643–2649. doi: 10.1007/s10008-013-2169-1

Kovalenko, V., Kotok, V. (2017). Obtaining of Ni-Al layered double hydroxide by slit diaphragm electrolyzer. Eastern-European Journal of Enterprise Technologies, 2 (6 (86)), 11–16. doi: 10.15587/1729-4061.2017.95699

Kovalenko, V. L., Kotok, V. A. (2015). The synthesis of nickel hydroxide by electrolysis from nickel nitrate solution in the slit diaphragm electrolyzer. Electrochemical properties. Collection of research papers of National mining university, 49, 181–186.

Kovalenko, V. L., Kotok, V. A., Malishev, V. V. (2008). Electrochemical obtaining of Ni(OH)2 from sulphate solution by flowing slit diafragm electrolyzer. RSE-SEE, 1st regional symposium on electrochemistry of South-East Europe, 201–203.

Kotok, V., Кovalenko, V. (2017). Optimization of nickel hydroxide electrode of the hybrid supercapacitor. Eastern-European Journal of Enterprise Technologies, 1 (6 (85)), 4–9. doi: 10.15587/1729-4061.2017.90810


Пристатейна бібліографія ГОСТ


Posada, J. O. G. Aqueous batteries as grid scale energy storage solutions [Text] / J. O. G. Posada, A.J.R. Rennie, S. P. Villar, V. L. Martins, J., Marinaccio, A.,Barnes, P. J. Hall, et. al // Renewable and Sustainable Energy Review. – 2017. – No. 68. – P. 1174–1182. doi: 10.1016/j.rser.2016.02.024

Hall, D. S. Raman and Infrared spectroscopy of α and β phases of thin nickel hydroxide films electrochemically formed on nickel [Text] / D. S. Hall, D. J. Lockwood, S. Poirier, C. Bock, B. R. MacDougall // The Journal of Physical Chemistry A. – 2012. – № 116 (25). – P. 6771–6784. doi: 10.1021/jp303546r

Hu, M. Structural transformation and its effects on the electrochemical performances of a layered double hydroxide[Text] / M. Hu, Z. Yang, L. Lei, Y. Sun // Journal of Power Sources. – 2011. – № 196 (3). – P. 1569–1577. doi: 10.1016/j.jpowsour.2010.08.041

Vidotti, M. Nickel hydroxide modified electrodes: a review study concerning its structural and electrochemical properties aiming the application in electrocatalysis, electrochromism and secondary batteries [Text] / M. Vidotti, R. Torresi, SIC. De Torresi // Quim Nova. – 2010. – Vol. 33, № 10. – P. 2176–2186.

Kovalenko, V. L. Nickel hydroxide obtained by high-temperature two-step synthesis as an effective material for supercapacitor applications [Text] / V. L. Kovalenko, V. A. Kotok, A. A. Sykchin, I. A. Mudryi, B. A. Ananchenko, A. A. Burkov, , V. A. Sololvov, S. Deabate, A. Mehdi, J.-L. Bantignies, F. Henn // Journal of Solid State Electrochemistry. – 2016. – № 21 (3).– P. 683 – 691. doi: 10.1007/s10008-016-3405-2

Kovalenko, V. Definition of factors influencing on Ni(OH)2 electrochemical characteristics for supercapacitors [Text] / V. Kovalenko, V. Kotok, A. Bolotin // Eastern-European Journal of Enterprise Technologies. – 2016. – № 5/6 (83). – P. 17–22. doi: 10.15587/1729-4061.2016.79406

Соловов, В. А. Mеханизм формирования гидроксида никеля в системе Ni(NO3)2–NaOH [Текст] / В. А. Соловов, Н. В., Николенко, В. Л. Коваленко, В. А. Коток, Д. В. Гиренко // Вестник НТУ «ХПИ». Серия: Новые решения в современных технологиях. – 2017. – № 7 (1229). – С. 199–204.

Ramesh, T. N. Synthesis of nickel hydroxide, Effect of precipitation conditions on phase selectivity and structural disorder [Text] / T. N. Ramesh, P. V. Kamath // Journal of Power Sources. – 2006. – № 156 (2). – P. 655–661. doi: 10.1016/j.jpowsour.2005.05.050

Hu, B. Controllable Synthesis of Zinc-Substituted α- and β-Nickel Hydroxide Nanostructures and Their Collective Intrinsic Properties [Text] / B. Hu, S.-F. Chen, S.-J. Liu // Chemistry - A European Journal. – 2008. – № 14 (29). – P. 8928 – 8938. doi: 10.1002/chem.200800458

Gong, L. Facile solvothermal synthesis Ni(OH)2 nanostructure for electrochemical capacitors [Text] / L. Gong, X. Liu, L. Su // Journal of Inorganic and Organometallic Polymers and Materials. – 2011. – № 21(4). – P. 866–870. doi: 10.1007/s10904-011-9519-1

Yang, L.-X. Hydrothermal synthesis of nickel hydroxide nanostructures in mixed solvents of water and alcohol [Text] / L.-X. Yang, Y.-J. Zhu, H. Tong, Z.-H. Liang, L. Li, L. Zhang // Journal of Solid State Chemistry. – 2007. – № 180 (7). – P. 2095 – 2101. doi: 10.1016/j.jssc.2007.05.009

Xu, L. 3D Flowerlike r-Nickel Hydroxide with Enhanced Electrochemical Activity Synthesized by Microwave-Assisted Hydrothermal Method [Text] / L. Xu, Y.-S. Ding, C.-H. Chen, L. Zhao, C. Rimkus, R. Joesten, S. L. Suib // Chemistry of Materials. – 2008. – № 20 (1). – P. 308–316. doi: 10.1021/cm702207w

Fomanyuk, S. S. Kinetics of electrochromic process in thin films of cathodically deposited nickel hydroxide [Text] / S. S. Fomanyuk, Y. S. Krasnov, G. Y. Kolbasov // Journal of Solid State Electrochemistry. – 2013. – № 17 (10). – P. 2643–2649. doi: 10.1007/s10008-013-2169-1

Kovalenko, V. Obtaining of Ni-Al layered double hydroxide by slit diaphragm electrolyzer [Text] / V. Kovalenko, V. Kotok // Eastern-European Journal of Enterprise Technologies. – 2017. – № 2/6 (86). – P. 11–16. doi: 10.15587/1729-4061.2017.95699

Kovalenko, V. L. The synthesis of nickel hydroxide by electrolysis from nickel nitrate solution in the slit diaphragm electrolyzer. Electrochemical properties [Text] / V. L. Kovalenko, V. A. Kotok // Collection of research papers of National mining university. – 2015 – № 49 – P. 181–186.

Кovalenko, V. L. Electrochemical obtaining of Ni(OH)2 from sulphate solution by flowing slit diafragm electrolyzer [Text]: Book of abstracts / V. L. Kovalenko, V. A. Kotok, V. V. Malishev // RSE-SEE, 1st regional symposium on electrochemistry of South-East Europ, 2008. – P. 201–203.

Kotok, V. Optimization of nickel hydroxide electrode of the hybrid supercapacitor [Text] / V. Kotok, V. Kovalenko // Eastern-European Journal of Enterprise Technology. – 2017. – № 1/6 (85). – P. 4–9. doi: 10.15587/1729-4061.2017.90810



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